Basic Examples

A permutation involution with
1↔2
,
3↔4
:
In[]:=
[◼]
PermutationInvolutionQ
@{2,1,4,3}
Out[]=
True
The permutation
{2,3,1}
is not an involution because
1↦2↦3≠1
:
In[]:=
[◼]
PermutationInvolutionQ
@{2,3,1}
Out[]=
False

Scope

These are the 10 involutive permutation on four elements, shown compactly:
In[]:=
Row/@SelectPermutations@Range@4,
[◼]
PermutationInvolutionQ

Out[]=
{1234,1243,1324,1432,2134,2143,3214,3412,4231,4321}